論文『メビウスカーボンナノベルトの合成』がNatureSynthesisに掲載されました

Synthesis of a Möbius carbon nanobelt

Yasutomo Segawa,* Tsugunori Watanabe, Kotono Yamanoue, Motonobu Kuwayama, Kosuke Watanabe, Kenichiro Itami*

Nature Synth. 2022, DOI: 10.1038/s44160-022-00075-8

ChemRxiv 2021, DOI: 10.26434/chemrxiv-2021-w09lc

 

New technologies for the creation of topological carbon nanostructures have significantly advanced synthetic organic chemistry and materials science. While simple molecular nanocarbons with a belt topology have been constructed recently, analogous carbon nanobelts with a twist, i.e., Möbius carbon nanobelts (MCNBs), have not yet been synthesized due to their high intrinsic strain. Herein, we report the synthesis, isolation, and characterization of a MCNB. Calculations of strain energies suggested that large MCNBs are synthetically accessible. Designing a macrocyclic precursor with an odd number of repeat units led to a successful rational synthetic route via Z-selective Wittig reactions and nickel-mediated intramolecular homocoupling reactions, which yielded (25,25)MCNB over 14 steps. NMR and theoretical calculations revealed that the twist moiety of the Möbius band moves quickly around the MCNB molecule in solution. The topological chirality originating from the Möbius structure was confirmed experimentally using chiral HPLC separation and CD spectroscopy.

分子科学研究所 生命・錯体分子科学研究領域

瀬川グループ

〒444-8787愛知県岡崎市明大寺町字東山5-1 山手キャンパス3号館4階西

Department of Life and Coordination-Complex Molecular Science, Institute for Molecular Science (IMS)

Segawa Group

Yamate Campus, Bldg. No. 3, 4F West
5-1 Higashiyama, Myodaiji, Okazaki, 444-8787, Japan

Copyright © Segawa Group
トップへ戻るボタン